Identification of the substancemixture and of the companyundertaking 1. Oct 08, 2014 toluene should be kept away from incompatible materials, like oxidizing agents. However, it is very poisonous and was used as a chemical weapon during world war i where it was. Phosgene is an acyl chloride obtained by substitution of both hydrogens of formaldehyde by chlorine. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of. Toluene mixes readily with many organic solvents, but. Phosgene is a major industrial chemical used to make plastics and pesticides. Not classifiable as to its carcinogenicity to humans toluene ntp. Hazards identification potential acute health effects. December 3, 2015 the dow chemical company page 3 of 8 u. Description toluene is a clear, colorless, volatile liquid with a sweet, pungent, benzenelike odor. Toluene cas no 108883 material safety data sheet sds msds. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Toluol, methylbenzene, phenylmethane company identification.
Phosgene cocl2 or ccl2o cid 6371 structure, chemical names, physical. Safety data sheet according to federal register vol. Fire hazard, immediate acute health hazard, delayed chronic health hazard. Phosgene cocl2 is used in organic synthesis, in manufacture of dyes, pharmaceuticals, herbicides, insecticides, synthetic foams, resins, and polymers.
Warning properties of the gas inhaled are slight, death. The standards were stored for about 16 h at room temperature before analysis. Safety data sheet according to 29cfr19101200 and ghs rev. For more information, call the atsdr information center at 18002324636. Material safety data sheet toluene, acs 1 section 1 chemical product and company identification msds name. Globally, approximately 75% of phosgene is consumed for isocyanates, 20% for polycarbonates, and about 5% for fine chemicals. Warning properties of the gas inhaled are slight, death may occur within 36. Toluene should be kept away from incompatible materials, like oxidizing agents. When liquid phosgene is released, it quickly turns into a gas that stays close to the ground and.
Basf 8e notification to epa dated february 3, 1998. Certificate of analysis coa specification sheet pdf. Phosgene cg reacts violently with strong oxidants, amines, alkalis, and many metals. This fact sheet answers the most frequently asked health questions faqs about toluene diisocyanate tdi and methylenediphenyl diisocyanate mdi. Phosgene solution in toluene material safety data sheet synonym. A registration number is not available for this substance as the substance. No action shall be taken involving any personal risk or without suitable training. Adequate ventilation to ensure that occupational exposure limits are not exceeded. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 psm 100x10e12 siemens per meter and is considered a semi conductive. Toluene diisocyanate and methylendiphenyl diisocyanate. Sigmaaldrich 244511 page 6 of 8 germ cell mutagenicity genotoxicity in vitro rat liver dna damage carcinogenicity iarc. Toluene wt, % min 99,2 benzene wt, % max 0,02 sulphur wt, % 0,25 section 3. Above 572f 300c, phosgene cg decomposes in the presence of moisture to form hydrochloric acid and carbon dioxide.
Slightly hazardous in case of skin contact permeator. Many reports of reproductive effects of toluene abuse or heavy occupational exposure are confounded by mixed solvent exposure or fetal alcohol syndrome. Ch 25 803 thioether 81 01 731 toluene 100a 81 01 421 toluene 100ad ch 23 001 toluene 5a. Signal word danger hazard statements h225 highly flammable liquid and vapour. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Osha no component of this product present at levels greater than or equal to 0. For more information about toluene uses, safety, or disposal, search our database of msds. This fact sheet is one in a series of summaries about hazardous substances and their health effects. Standards were prepared by injecting phosgene gas into the headspace of several 2ml glass vials, each containing 1 ml of a solution of 15 mgml 2hmp in toluene. Cas 75445 108883 phosgene solution, 20% in toluene, 79380 phosgene carbonyl chloride sara 3023 cercla toluene sara 3 cercla supdat. Chronic exposure to phosgene compounds may cause irreversible pulmonary.
Toluene material safety data sheet cas no 108883 sdsmsds. Triphosgene bistrichloromethyl carbonate btc is a chemical compound with the formula ococcl32. Phosgene is the organic chemical compound with the formula cocl2. Safety data sheet northwest missouri state university. With cooling and pressure, phosgene gas can be converted into a liquid so that it can be shipped and stored.
Toluene diisocyanate and methylendiphenyl diisocyanatetoxfaqs. If medical advice is needed, have product container or label at hand keep out of reach of children read label before use. No component of this product present at levels greater than or equal to 0. Methods and material for containment and cleaning up. Toluene crosses the placenta and is excreted in breast milk. It is also produced in the presence of refrigerants that are drawn through a heat source, refrigeation technicians should take extreme caution and prevent the exposure by. The major pathological feature is delayed pulmonary edema. Soluble in benzene, carbon tetrachloride, chloroform, toluene, and acetic acid. The overall reaction of toluene diamine with phosgene to form.
Hazardous in case of skin contact irritant, of eye contact irritant, of ingestion, of inhalation. Product identifier product name toluene product number toen reach registration number 012119471051xxxx cas number 108883 eu index number 601021003 ec number 2036259 1. Phosgene appears as a colorless gas or very lowboiling, volatile liquid b. Whether you use toluene at work or in household products, safety is of the utmost importance when handling this hazardous chemical. Hazards identification classification this chemical is considered hazardous by the 2012 osha hazard communication standard 29 cfr 1910. Methylbenzene recommended use laboratory chemicals. Chemical product and company identification product name. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. At room temperature 70f, phosgene is a poisonous gas. Saba, dizon, kasih, stewart 10 slow to be recognized, as phosgene can only be detected at 0. Toluene safety data sheet according to federal register vol.
Phosgene is a valued industrial building block, especially for the production of urethanes and polycarbonate plastics. Disclaimer of liability the information in this msds was obtained from sources which we believe are reliable. Contact with water or moist air may form flammable andor toxic gases of. Toluene 108883 toluene in blood prior to last shift of workweek 0. Signs and symptoms of toxicity may be delayed for 24 hours. Draeger tubes which are not classified as dangerous goods. Chlorine and phosgene are used in the synthesis of tdi and are not expected to be present in user facilities. Unlikely under normal occupational exposures, but swallowing a minor amount may result in nausea, vomiting, shortness of breath, headache, diarrhoea and abdominal discomfort. Bulletin about triphosgene material safety data sheet. Toluene sara 3112 msds distribution chemical inventory hazard identification. Labchem inc 200 william pitt way pittsburgh, pa 15238 company phone number. Msds phosgene solution, 20% in toluene, 79380 phosgene. It is flammable at temperatures greater than 40 ef 4.
The product is low in sulfur, but the composition may vary depending on the cracker feedstock and conditions. Details of the supplier of the safety data sheet emergency telephone number chemtreco, inside the usa. Toluenexylene mix is a liquid that ranges from clear to yellow in color, with a moderate to strong aromatic or camphorlike odor. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or. The products of degradation are less toxic than the product itself. Phosgene is the organic chemical compound with the formula cocl 2. With water, phosgene reacts to form carbon dioxide and hydrochloric acid. Safety data sheet creation date 11jun2009 revision date 17jan2018 revision number 4 1.